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The tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl thallium compound, [TismPriBenz]Tl, reacts with Li, Na, K and Rb afford the respective alkali metal carbatrane complex, [TismPriBenz]M (M = Li, Na, K, Rb), while the cesium complex [TismPriBenz]Cs is obtained via the reaction of [TismPriBenz]Li with CsF. These carbatrane compounds [TismPriBenz]M (M = Li, Na, K, Rb and Cs) constitute the first complete series of structurally characterized monomeric alkyl compounds of the nonradioactive alkali metals.more » « less
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Wan, Yanjun; Adda, Augustine K; Qian, Jin; Vaccaro, David A; He, Peixian; Li, Gang; Norton, Jack R (, Journal of the American Chemical Society)
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Shlian, Daniel G.; Pelaez, James; Vaccaro, David A.; Parkin, Gerard (, Journal of Molecular Structure)
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Hammond, Matthew; Vaccaro, David A.; Parkin, Gerard (, Polyhedron)
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